Makromolekulare Chemie II - AG Schmalz

    Dr. Holger Schmalz

Publikationsliste


-- 2013 --
Kuttner, C.; Hanisch, A.; Schmalz, H.; Eder, M.; Schlaad, H.; Burgert, I.; Fery, A.
"Influence of the Polymeric Interphase Design on the Interfacial Properties of (Fiber-Reinforced) Composites"
ACS Appl. Mater. Interf. 2013, 5, 2469.

-- doi:10.1021/am302694h     
Schmelz, J.; Schacher, F.H.; Schmalz, H.
"Cylindrical Crystalline-Core Micelles: Pushing the Limits of Solution Self-Assembly"
Soft Matter 2013, 9, 2101.

-- doi:10.1039/C2SM27259H     

-- 2012 --
Hanisch, A.; Schmalz, H.; Müller, A.H.E.
"A Modular Route for the Synthesis of ABC Miktoarm Star Terpolymers via a New Alkyne-Substituted Diphenylethylene Derivative"
Macromolecules 2012, 45, 8300.

-- doi:10.1021/ma3017579
Schmelz, J.; Schedl, A.E.; Steinlein, C.; Manners, I.; Schmalz, H.
"Length Control and Block-Type Architectures in Worm-like Micelles with Polyethylene Cores"
J. Am. Chem. Soc. 2012, 134, 14217.

-- doi:10.1021/ja306264d     
Gröschel, A.H.; Walther, A.; Löbling, T.; Schmelz, J.; Hanisch, A.; Schmalz, H.; Müller, A.H.E.
"Facile, Solution-Based Synthesis of Soft, Nanoscale Janus Particles with Tunable Janus Balance"
J. Am. Chem. Soc. 2012, 134, 13850.

-- doi:10.1021/ja305903u     
Schmelz, J.; Schmalz, H.
"Corona Structure on Demand: Tailor-Made Surface Compartmentalization in Worm-Like Micelles via Random Cocrystallization"
Polymer 2012, 53, 4333.

-- doi:10.1016/j.polymer.2012.07.058
Rosenfeldt, S.; Lüdel, F.; Schulreich, C.; Hellweg, T.; Radulescu, A.; Schmelz, J.; Schmalz, H.; Harnau, L.
"Patchy Worm-Like Micelles: Solution Structure Studied by Small-Angle Neutron Scattering"
Phys. Chem. Chem. Phys. 2012, 14, 12750.

-- doi:10.1039/C2CP41231D
Schmalz, A.; Schmalz, H.; Müller, A.H.E.
"Double Responsive Hydrogels Based on Tertiary Amine Methacrylate Star Block Copolymers"
Z. Physik. Chem. 2012, 226, 695.

-- doi:10.1524/zpch.2012.0240     
Schmalz, A.; Schmalz, H.; Müller, A.H.E.
"Smart Hydrogels Based on Responsive Star-Block Copolymers"
Soft Matter 2012, 8, 9436.

-- doi:10.1039/C2SM25686J     
Majewski, A.; Schallon, A.; Jérôme, V.; Freitag, R.; Müller, A.H.E.; Schmalz, H.
"Dual-Responsive Magnetic Core-Shell Nanoparticles for Non-Viral Gene Delivery and Cell Separation"
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2012, 53(1), 595. -- Details
Majewski, A.; Schallon, A.; Jérôme, V.; Freitag, R.; Müller, A.H.E.; Schmalz, H.
"Dual-Responsive Magnetic Core-Shell Nanoparticles for Non-Viral Gene Delivery and Cell Separation"
Biomacromolecules 2012, 13, 857.

-- doi:10.1021/bm2017756     
Gröschel, A.H.; Schacher, F.H.; Schmalz, H.; Borisov, O.V.; Zhulina, E.B.; Walther, A.; Müller, A.H.E.
"Precise Hierarchical Self-Assembly of Multicompartment Micelles"
Nat. Commun. 2012, 3, 710.

-- doi:10.1038/ncomms1707     
Mihut, A.; Crassous, J.; Schmalz, H.; Drechsler, M.; Ballauff, M.
"Self-Assembly of Crystalline-Coil Diblock Copolymers in Solution: Experimental Phase Map"
Soft Matter 2012, 8, 3163.

-- doi:10.1039/C2SM06359J     

-- 2011 --
Schmelz, J.; Karg, M.; Hellweg, T.; Schmalz, H.
"General Pathway toward Crystalline-Core Micelles with Tunable Morphology and Corona Segregation"
ACS Nano 2011, 5, 9523.

-- doi:10.1021/nn202638t     
Pfaff, A.; Schallon, A.; Ruhland, T.; Majewski, A.; Schmalz, H.; Freitag, R.; Müller, A.H.E.
"Magnetic and Fluorescent Glycopolymer Hybrid Nanoparticles for Intranuclear Optical Imaging"
Biomacromolecules 2011, 12, 3805.

-- doi:10.1021/bm201051p     
Babin, I.A.; Pergushov, D.V.; Wolf, A.; Plamper, F.A.; Schmalz, H.; Müller, A.H.E.; Zezin, A.B.
"Micellar Interpolyelectrolyte Complexes Formed by Star-Shaped Poly(acrylic acid) with Double Hydrophilic Cationic Diblock Copolymer"
Doklady Phys. Chem. 2011, 441, 219.

-- doi:10.1134/S0012501611110030     
Müller, A.H.E.; Majewski, A.; Reinicke, S.; Schmalz, A.; Schmalz, H.
"New Block Copolymers, Stars, and Hybrid Particles for Smart Hydrogels"
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2011, 52(2), 800. -- Details
Karg, M.; Reinicke, S.; Lapp, A.; Hellweg, T.; Schmalz, H.
"Temperature-dependent gelation behaviour of double responsive P2VP-b-PEO-b-P(GME-co-EGE) triblock terpolymers: A SANS study"
Macromol. Symp. 2011, 306-307, 77.

-- doi:10.1002/masy.201000142
Reinicke, S.; Schmalz, H.
"Combination of living anionic polymerization and ATRP via “click” chemistry as a versatile route to multiple responsive triblock terpolymers and corresponding hydrogels"
Colloid Polym. Sci. 2011, 289, 497.

-- doi:10.1007/s00396-010-2359-7     

-- 2010 --
Krekhova, M.; Lang, T.; Richter, R.; Schmalz, H.
"Thermo-reversible hydroferrogels with tunable mechanical properties utilizing block copolymer mesophases as template"
Langmuir 2010, 26, 19181.

-- doi:10.1021/la1040823     
Reinicke, S.; Karg, M.; Lapp, A.; Heymann, L.; Hellweg, T.; Schmalz, H.
"Flow induced ordering in cubic gels formed by P2VP-b-PEO-b-P(GME-co-EGE) triblock terpolymer micelles: A rheo-SANS study"
Macromolecules 2010, 43, 10045.

-- doi:10.1021/ma101768b
Krekhova, M.; Lattermann, G.; Schmalz, H.; Lang, T.; Richter, R.
"Towards softer thermo-reversible magnetogels"
Physics Procedia 2010, 9, 224.

-- doi:10.1016/j.phpro.2010.11.050     
Reinicke, S.; Döhler, S.; Tea, S.; Krekhova, M.; Messing, R.; Schmidt, A.M.; Schmalz, H.
"Magneto-responsive hydrogels based on maghemite/triblock terpolymer hybrid micelles"
Soft Matter 2010, 6, 2760.

-- doi:10.1039/c000943a     
Plamper, F.A.; Reinicke, S.; Elomaa, M.; Schmalz, H.; Tenhu, H.
"Pearl Necklace Architecture: Novel Threaded Star-Shaped Copolymers"
Macromolecules 2010, 43, 2190.

-- doi:10.1021/ma902568d
Mihut, A.; Crassous, J.; Schmalz, H.; Ballauff, M.
"Crystallization-Induced Aggregation of Block Copolymer Micelles: Influence of Crystallization Kinetics on Morphology"
Colloid Polym. Sci. 2010, 288, 573.

-- doi:10.1007/s00396-010-2185-y     
Schmalz, A.; Hanisch, M.; Schmalz, H.; Müller, A.H.E.
"Double Stimuli-Responsive Behavior of Linear and Star-Shaped Poly(N,N-Diethylaminoethyl Methacrylate) in Aqueous Solution"
Polymer 2010, 51, 1213.

-- doi:10.1016/j.polymer.2009.11.023
Ruckdäschel, H.; Gutmann, P.; Altstädt, V.; Schmalz, H.; Müller, A.H.E.
"Foaming of Micro- and Nanostructured Polymer Blends"
Adv. Polym. Sci. 2010, 227, 199.

-- doi:10.1007/12_2009_32     

-- 2009 --
Schacher, F.H.; Walther, A.; Betthausen, E.; Schmalz, H.; Pergushov, D.V.; Müller, A.H.E.
"Interpolyelectrolyte Complexes of Dynamic Multicompartment Micelles"
ACS Nano 2009, 3, 2095.

-- doi:10.1021/nn900110s     
Yuan, J.; Lu, Y.; Schacher, F.H.; Lunkenbein, T.; Weiß, S.; Schmalz, H.; Müller, A.H.E.
"Template-directed Synthesis of Titania Hybrid Nanowires within Bishydrophilic Core-Shell Cylindrical Polymer Brushes"
Chem. Mater. 2009, 21, 4146.

-- doi:10.1021/cm900032m     
Schacher, F.H.; Reinicke, S.; Walther, A.; Schmalz, H.; Müller, A.H.E.: New Amphiphilic Nanostructures Based on Block Terpolymers Made by Anionic Polymerization in E. Khosravi, Y. Yagci, Eds.: New Smart Materials via Metal Mediated Macromolecular Engineering: From Complex to Nano Structures, NATO Science for Peace and Security Series, Springer, Dortrecht, 167, ISBN 978-90-481-3276-8 (2009), doi:10.1007/978-90-481-3278-2_10 -- Details
Reinicke, S.; Schmelz, J.; Lapp, A.; Karg, M.; Hellweg, T.; Schmalz, H.
"Smart Hydrogels Based on Double Responsive Triblock Terpolymers"
Soft Matter 2009, 5, 2648.

-- doi:10.1039/b900539k     
Joso, R.; Reinicke, S.; Walther, A.; Schmalz, H.; Müller, A.H.E.; Barner, L.
"Facile Access to Hydroxy-Functional Core/Shell Microspheres via Grafting of Ethylene Oxide by Anionic Ring Opening Polymerization"
Macromol. Rapid Commun. 2009, 30, 1009.

-- doi:10.1002/marc.200900031     
Schumacher, M.; Ruppel, M.; Yuan, J.; Schmalz, H.; Colombani, O.; Drechsler, M.; Müller, A.H.E.
"Smart Organic-Inorganic Nanohybrids Based on Amphiphilic Block Copolymer Micelles and Functional Silsesquioxane Nanoparticles"
Langmuir 2009, 25, 3407.

-- doi:10.1021/la803601a     
Pergushov, D.V.; Babin, I.A.; Plamper, F.A.; Schmalz, H.; Müller, A.H.E.
"Water-Soluble Complex Macromolecular Structures Based on Star-Shaped Poly(acrylic acid)"
Doklady Phys. Chem. 2009, 425, 57.

-- doi:10.1134/S0012501609030038     
Schacher, F.H.; Müllner, M.; Schmalz, H.; Müller, A.H.E.
"New Block Copolymers with Poly(N,N-dimethylaminoethyl methacrylate) as Double Stimuli-Responsive Block"
Macromol. Chem. Phys. 2009, 210, 256.

-- doi:10.1002/macp.200800557      
Mihut, A.; Chiche, A.; Drechsler, M.; Schmalz, H.; Di Cola, Emanuela; Krausch, G.; Ballauff, M.
"Crystallization-induced switching of the morphology of poly(ethylene oxide)-block-polybutadiene micelles "
Soft Matter 2009, 5, 208.

-- doi:10.1039/b810415h     

-- 2008 --
Ruckdäschel, H.; Rausch, J.; Sandler, J.K.W.; Altstädt, V.; Schmalz, H.; Müller, A.H.E.
"Correlation of the Melt Rheological Properties With the Foaming Behavior of Immiscible Blends of Poly(2,6-dimethyl-1,4-phenylene ether) and Poly(styrene-co-acrylonitrile)"
Polymer Engineering and Science 2008, 48, 2111.

-- doi:10.1002/pen.21100     
Reinicke, S.; Schmelz, J.; Schmalz, H.
"pH- and Temperature-Sensitive Hydrogels Based on Triblock Terpolymers"
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2008, 49(2), 459. -- Details
Schmelz, J.; Drechsler, M.; Yuan, J.; Walther, A.; Schmalz, H.
"Surface-Compartmentalized Nanostructures via Crystallization Induced Self-Assembly of Triblock Terpolymers"
Polym. Mater. Sci. Eng. 2008, 99, 680. -- Details
Yuan, J.; Xu, Y.; Walther, A.; Bolisetty, S.; Schumacher, M.; Schmalz, H.; Ballauff, M.; Müller, A.H.E.
"Water-Soluble Organo-Silica Hybrid Nanowires"
Nat. Mater. 2008, 7, 718.

-- doi:10.1038/nmat2232     
Ruckdäschel, H.; Gutmann, P.; Altstädt, V.; Schmalz, H.; Müller, A.H.E.
"Development of Micro- and Nanocellular Polymer Foams"
Mat. Res. Soc. Symp. Proc. 2008, 1056E, H11-75. -- Details
Walther, A.; Goldmann, A.S.; Yelamanchili, R.S.; Drechsler, M.; Schmalz, H.; Eisenberg, A.; Müller, A.H.E.
"Multiple Morphologies, Phase Transitions and Crosslinking of Crew-Cut Aggregates of Polybutadiene-block-Poly(2-vinylpyridine) Diblock Copolymers"
Macromolecules 2008, 41, 3254.

-- doi:10.1021/ma7026148
Schmalz, H.; Schmelz, J.; Drechsler, M.; Yuan, J.; Walther, A.; Schweimer, K.; Mihut, A.
"Thermo-Reversible Formation of Wormlike Micelles with a Microphase-Separated Corona from a Semicrystalline Triblock Terpolymer"
Macromolecules 2008, 41, 3235.

-- doi:10.1021/ma702417y
Yuan, J.; Xu, Y.; Schumacher, M.; Schmalz, H.; Müller, A.H.E.
"Core-shell Cylindrical Polymer Brushes With Silica Nanowire Core"
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2008, 49 (1), 21. -- Details
Castillo, R.V.; Arnal, M. L.; Müller, A. J.; Hamley, I. W.; Castelletto, V.; Schmalz, H.; Abetz, V.
"Fractionated Crystallization and Fractionated Melting of Confined PEO Microdomains in PB-b-PEO and PE-b-PEO Diblock Copolymers"
Macromolecules 2008, 41, 879.

-- doi:10.1021/ma0718907
Boschetti-de-Fierro, A.; Lorenzo, A. T.; Müller, A. J.; Schmalz, H.; Abetz, V.
"Crystallization Kinetics of PEO and PE in Different Triblock Terpolymers: Effect of Microdomain Geometry and Confinement"
Macromol. Chem. Phys. 2008, 209, 476.

-- doi:10.1002/macp.200700434     
Yuan, J.; Schmalz, H.; Xu, Y.; Miyajima, N.; Drechsler, M.; Möller, M.W.; Schacher, F.H.; Müller, A.H.E.
"Room-temperature growth of uniform tellurium nanorods and the assembly of tellurium or Fe3O4 nanoparticles on the nanorods"
Adv. Mater. 2008, 20, 947.

-- doi:10.1002/adma.200701756     

-- 2007 --
Ah Toy, A..; Reinicke, S.; Müller, A.H.E.; Schmalz, H.
"One-pot Synthesis of Polyglycidol Containing Block Copolymers with Alkyllithium Initiators Using the Phosphazene Base t-BuP4"
Macromolecules 2007, 40, 5241.

-- doi:10.1021/ma070672a
Ruckdäschel, H.; Sandler, J.K.W.; Altstädt, V.; Rettig, C.; Schmalz, H.; Abetz, V.; Müller, A.H.E.
"Toughening of Immiscible PPE/SAN Blends by Triblock Terpolymers"
Polymer 2007, 48, 2700.

-- doi:10.1016/j.polymer.2007.03.005
Ruckdäschel, H.; Rausch, J.; Sandler, J.K.W.; Altstädt, V.; Schmalz, H.; Müller, A.H.E.
"Foaming of Miscible and Immiscible Polymer Blends"
Mat. Res. Soc. Symp. Proc. 2007, 977E.

-- PDF

-- 2006 --
Voets, I.K.; de Keizer, A.; de Waard, P.; Frederik, P.M.; Bomans, P.H.H.; Schmalz, H.; Walther, A.; King, S.M.; Leermakers, F.A.M.; Cohen Stuart, M.A.
"Double-faced Micelles from Water-soluble Polymers"
Angew. Chem., Int. Ed. 2006, 45, 6673.

-- doi:10.1002/anie.200601000     
Vivas, M.; Contreras, J.; Lopez-Carrasquero, F.; Lorenzo, A. T.; Arnal, M. L.; Balsamo, V.; Müller, A. J.; Laredo, E.; Schmalz, H.; Abetz, V.
"Synthesis and Characterization of Triblock Terpolymers with Three Potentially Crystallizable Blocks: Polyethylene-b-Poly(ethylene oxide)-b-Poly(ε-caprolactone)"
Macromol. Symp. 2006, 239, 58.

-- doi:10.1002/masy.200690110     
Nosov, S.; Schmalz, H.; Müller, A.H.E.
"One-pot Synthesis of Primary Amino End-functionalized Polymers by Reaction of Living Anionic Polybutadienes with Nitriles"
Polymer 2006, 47, 4245.

-- doi:10.1016/j.polymer.2006.04.018
Ruckdäschel, H.; Sandler, J.K.W.; Altstädt, V.; Rettig, C.; Schmalz, H.; Abetz, V.; Müller, A.H.E.
"Compatibilisation of PPE/SAN Blends by Triblock Terpolymers: Correlation Between Block Terpolymer Composition, Morphology and Properties"
Polymer 2006, 47, 2772.

-- doi:10.1016/j.polymer.2006.02.064

-- 2005 --
Schmalz, H.; Abetz, V.
"ABC Triblock Terpolymers with One ore Two Crystallisable Blocks: Mechanical Properties and Crystallisation Behavior"
Proceedings, 2nd Workshop of the Young European Scientists (YES 2005), Cracow, September 2005.

-- PDF

-- 2004 --
Zettl, H.; Häfner, W.; Böker, A.; Schmalz, H.; Lanzendörfer, M.; Müller, A.H.E.; Krausch, G.
"Fluorescence Correlation Spectroscopy of Single Dye-Labeled Polymers in Organic Solvents"
Macromolecules 2004, 37, 1917.

-- 2003 --
Schmalz, H.; Abetz, V.; Lange, R.
"Thermoplastic Elastomers Based on Semicrystalline Block Copolymers"
Composites Sci. Technol. 2003, 63, 1179.
Schmalz, H.; Lanzendörfer, M.; Abetz, V.; Müller, A.H.E.
"Anionic Polymerization of Ethylene Oxide in the Presence of the Phosphazene Base t-BuP4 - Kinetic Investigations Using In-Situ FT-NIR Spectroscopy and MALDI-ToF MS"
Macromol. Chem. Phys. 2003, 204, 1056.
Schmalz, H.; Müller, A. J.; Abetz, V.
"Crystallization in ABC Triblock Copolymers With Two Different Crystalline End Blocks: Influence of Confinement on Self-Nucleation Behavior"
Macromol. Chem. Phys. 2003, 204, 111.

-- 2002 --
Lanzendörfer, M.; Schmalz, H.; Abetz, V.; Müller, A.H.E.: Application of FT-NIR Spectroscopy for Monitoring the Kinetics of Living Polymerizations in J.E. Puskas, R. Storey, Eds.: In-situ Spectroscopy of Monomer and Polymer Synthesis, Kluwer Academic/Plenum Publishers, New York/Dordrecht, 67-82 (2002)
Schmalz, H.; Knoll, A.; Müller, A. J.; Abetz, V.
"Crystallization Behavior of End Blocks in ABC Triblock Copolymers"
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2002, 43, 371.
Schmalz, H.; Knoll, A.; Müller, A. J.; Abetz, V.
"Synthesis and Characterization of ABC Triblock Copolymers with Two Different Crystalline End Blocks: Influence of Confinement on Crystallization Behavior and Morphology"
Macromolecules 2002, 35, 10004.
Gabriëlse, W.; van Guldener, V.; Schmalz, H.; Abetz, V.; Lange, R.
"Morphology and Molecular Miscibility of Segmented Copoly(ether ester)s with Improved Elastic Properties As Studied by Solid State NMR"
Macromolecules 2002, 35, 6946.
Schmalz, H.; van Guldener, V.; Gabriëlse, W.; Lange, R.; Abetz, V.
"Morphology, Surface Structure, and Elastic Properties of PBT-Based Copolyesters with PEO-b-PEB-b-PEO Triblock Copolymer Soft Segments"
Macromolecules 2002, 35, 5491.
Müller, A. J.; Balsamo, V.; Arnal, M. L.; Jakob, T.; Schmalz, H.; Abetz, V.
"Homogeneous Nucleation and Fractionated Crystallization in Block Copolymers"
Macromolecules 2002, 35, 3048.
Schmalz, H.; Abetz, V.; Müller, A. J.
"Thermal and Self-Nucleation Behavior of Molecular Complexes Formed by p-Nitrophenol and the Poly(ethylene oxide) End Block Within an ABC Triblock Copolymer"
Macromol. Symp. 2002, 183, 179.

-- 2001 --
Lanzendörfer, M.; Schmalz, H.; Abetz, V.; Müller, A.H.E.
"Application of FT-NIR Spectroscopy for Monitoring the Kinetics of Living Polymerizations"
Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2001, 42, 329.
Schmalz, H.; Böker, A.; Lange, R.; Abetz, V.
"ABC Triblock Copolymers with Crystalline End Blocks and their Use as Thermoplastic Elastomers"
Polym. Mater. Sci. Eng. 2001, 8, 478.
Schmalz, H.; Böker, A.; Lange, R.; Krausch, G.; Abetz, V.
"Synthesis and Properties of ABA and ABC Triblock Copolymers with Glassy (A), Elastomeric (B), and Crystalline (C) Blocks"
Macromolecules 2001, 34, 8720.
Arnal, M. L.; Balsamo, V.; Lopez-Carrasquero, F.; Contreras, J.; Carrillo, M.; Schmalz, H.; Abetz, V.; Laredo, E.; Müller, A. J.
"Synthesis and Characterization of Polystyrene-b-poly(ethylene oxide)-b-poly(ε-caprolactone) Block Copolymers"
Macromolecules 2001, 34, 7973.
Schmalz, H.; Abetz, V.; Lange, R.; Soliman, M.
"New Thermoplastic Elastomers by Incorporation of Nonpolar Soft Segments in PBT-Based Copolyesters"
Macromolecules 2001, 34, 795.

-- 2000 --
Fletcher, M. D.; Harding, J. R.; Hughes, R. A.; Kelly, N. M.; Schmalz, H.; Sutherland, A.; Willis, C. L.
"Three Approaches to the Synthesis of L-leucine Selectively Labeled with Carbon-13 or Deuterium in Either Diastereotopic Methyl Group"
Perkin 1 2000, (1), 43.

-- 1998 --
Stock, N.; Schmalz, H.; Schnick, W.
"Synthesis, Structure, and Properties of Three Tetrasodium Tetrametaphosphimate Hydrates"
Z. Anorg. Allg. Chem. 1998, 624, 1777.

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