| EU MCRTN-CT-2003-505027: Self-Organized Nanostructures of Amphiphilic Copolymers (POLYAMPHI) |
| Von 03/2004 bis 02/2008 |
| Projektleiter: Axel H. E. Müller, Matthias Ballauff |
| Mitarbeiter: Oleg V. Borisov, Dmitry V. Pergushov, Holger Schmalz, Pierre-Eric Millard, Evis K. Penott-Chang |
| Abstract: In dem Marie Curie Research Training Network "Polyamphi" arbeiten neben zwei Gruppen der Universität Bayreuth (Lehrstühle MC II und PC I) noch 11 weitere Forschungsgruppen aus ganz Europa. Das Budget dieses Forschungsprojektes beträgt 2,7 Mio Euro. Das Netzwerk beschäftigt sich mit der Selbstorganisation amphiphiler Makromoleküle unterschiedlichster Architektur, wie z. B. Blockcopolymere, Pfropfcopolymere und komplexe Nanopartikel (Kern-Schale Struktur, Janus-Struktur), in wässeriger Lösung. Die Selbstorganisation kann hierbei durch verschiedenartige anziehende und abstoßende Wechselwirkungen hervorgerufen werden, die sich in ihrer Stärke und Reichweite unterscheiden: elektrostatisch, hydrophob/hydrophil, Wasserstoff-brückenbindungen, Metallkoordination. Der Fokus des Projektes liegt primär auf dem Verständnis des für die Strukturbildung entscheidenden Wechselspiels zwischen Makromolekülarchitektur und Art und Stärke der konkurrierenden Wechselwirkungen. "Polyamphi" nimmt sich die Natur als Vorbild, die über Selbstorganisation von amphiphilen Molekülen verschiedenartigste Strukturen auf makro- und supramolekularer Ebene erzeugen kann. Das ultimative Ziel ist daher die Entwicklung von Systemen, die in der Lage sind sich in einer hierarchischen Art und Weise zu organisieren. |
Publikationsliste dieses Projekts
| 390. Pergushov, D.V.; Borisov, O.V.; Zezin, A.B.; Müller, A.H.E.: Interpolyelectrolyte Complexes Based on Polyionic Species of Branched Topology, Adv. Polym. Sci. 241, 131 (2011) -- DOI: 10.1007/12_2010_102 -- Details |
| 388. Borisov, O.V.; Zhulina, E.B.; Leermakers, F.A.M.; Ballauff, M.; Müller, A.H.E.: Conformations and Solution Properties of Star-Branched Polyelectrolytes, Adv. Polym. Sci. 241, 1 (2011) -- DOI: 10.1007/12_2010_104 -- Details |
| 361. Xu, Y.; Borisov, O.V.; Ballauff, M.; Müller, A.H.E.: Manipulating the Morphologies of Cylindrical Polyelectrolyte Brushes by Forming Interpolyelectrolyte Complexes with Oppositely Charged Linear Polyelectrolytes: An AFM Study, Langmuir 26(10), 6919 (2010) -- DOI: 10.1021/la904167r -- Details |
| 358. Penott-Chang, E.K.; Pergushov, D.V.; Zezin, A.B.; Müller, A.H.E.: Interpolyelectrolyte Complexation in Chloroform, Langmuir 26(11), 7813 (2010) -- DOI: 10.1021/la904610w -- Details |
| 354. Lejeune, E.; Drechsler, M.; Jestin, J.; Müller, A.H.E.; Chassenieux, Ch.; Colombani, O.: Amphiphilic Diblock Copolymers with a Moderately Hydrophobic Block: Toward Dynamic Micelles, Macromolecules 43(6), 2667 (2010) -- DOI: 10.1021/ma902822g |
| 298. Pergushov, D.V.; Babin, I.A.; Plamper, F.A.; Zezin, A.B.; Müller, A.H.E.: Water-Soluble Complexes of Star-Shaped Poly(acrylic acid) With Quaternized Poly(4-vinylpyridine), Langmuir 24(13), 6414 (2008) -- DOI: 10.1021/la800959s -- PDF -- Details |
| 296. Walther, A.; Göldel, A.; Müller, A.H.E.: Controlled crosslinking of polybutadiene containing block terpolymer bulk structures: A facile way towards complex and functional nanostructures, Polymer 49, 3217 (2008) -- DOI: 10.1016/j.polymer.2008.05.023 -- PDF -- Details |
| 294. Hofs, B.; de Keizer, A.; van der Burgh, S.; Leermakers, F.A.M.; Cohen Stuart, M.A.; Millard, P.-E.; Müller, A.H.E.: Complex coacervate core micro-emulsions, Soft Matter 4, 1473 (2008) -- DOI: 10.1039/b802148a -- PDF -- Details |
| 293. Polotsky, A.; Charlaganov, M.; Xu, Y.; Leermakers, F.A.M.; Daoud, M.; Müller, A.H.E.; Dotera, T.; Borisov, O.V.: Pearl-necklace structures in core-shell molecular brushes: Experiments, Monte-Carlo simulations, and self-consistent field modeling, Macromolecules 41, 4020 (2008) -- DOI: 10.1021/ma800125q -- PDF -- Details |
| 292. Casse, O.; Colombani, O.; Kita-Tokarczyk, K.; Müller, A.H.E.; Meier, W.; Taubert, A.: Calcium phosphate mineralization beneath monolayers of poly(n-butyl acrylate)-block-poly(acrylic acid) block copolymers, Faraday Discussions 139, 179 (2008) -- DOI: 10.1039/b716353c -- PDF -- Details |
| 290. Walther, A.; Goldmann, A.S.; Yelamanchili, R.S.; Drechsler, M.; Schmalz, H.; Eisenberg, A.; Müller, A.H.E.: Multiple Morphologies, Phase Transitions and Cross-Linking of Crew-Cut Aggregates of Polybutadiene-block-Poly(2-vinylpyridine) Diblock Copolymers, Macromolecules 41, 3254 (2008) -- DOI: 10.1021/ma7026148 -- PDF -- Details |
| 281. Burkhardt, M.; Ruppel, M.; Pfaff, S.; Drechsler, M.; Schweins, R.; Pergushov, D.V.; Gradzielski, M.; Zezin, A.B.; Müller, A.H.E.: Water-Soluble Interpolyelectrolyte Complexes of Polyisobutylene-block-Poly(methacrylic acid) Micelles: Formation and Properties, Langmuir 24, 1769 (2008) -- DOI: 10.1021/la701835r -- PDF -- Details |
| 276. Burkhardt, M.; Martinez-Castro, N.; Pfaff, S.; Drechsler, M.; Babin, I.A.; Grishagin, I.V.; Schweins, R.; Pergushov, D.V.; Gradzielski, M.; Zezin, A.B.; Müller, A.H.E.: Polyisobutylene-block-poly(methacrylic acid) Diblock Copolymers: Self-Assembly in Aqueous Media, Langmuir 23, 12864 (2007) -- Details |
| 268. Colombani, O.; Ruppel, M.; Burkhardt, M.; Drechsler, M.; Schumacher, M.; Gradzielski, M.; Schweins, R.; Müller, A.H.E.: Structure of Micelles of Poly(n-butyl acrylate)-block-poly(acrylic acid) Diblock Copolymers in Aqueous Solution, Macromolecules 40, 4351 (2007) -- Details |
| 267. Colombani, O.; Ruppel, M.; Schubert, F.; Zettl, H.; Pergushov, D.V.; Müller, A.H.E.: Synthesis of Poly(n-butyl acrylate)-block-poly(acrylic acid) Diblock Copolymers by ATRP and Their Micellization in Water, Macromolecules 40, 4338 (2007) -- Details |
| 239. Eghbali, E.; Colombani, O.; Drechsler, M.; Müller, A.H.E.; Hoffmann, H.: Rheology and Phase Behavior of Poly(n-Butyl Acrylate)-block-Poly(Acrylic Acid) in Aqueous Solution, Langmuir 22, 4766-4776 (2006) -- Details |
| 237. André, X.; Benmohammed, Kh.; Litvinenko, G. I.; Yakimansky, A.V.; Müller, A.H.E.: Anionic Polymerization and Block Copolymerization of N,N-Diethylacrylamide in the Presence of Triethylaluminium. Kinetic Investigation Using In-line FT-NIR Spectroscopy, Macromolecules 39, 2773-2787 (2006) -- Details |
| 233. Martínez-Castro, N.; Zhang, M.; Pergushov, D.V.; Müller, A.H.E.: Anionic Polymerization of N,N-Dimethylacrylamide with Thienyllithium and Synthesis of Block Copolymers of Isobutylene and N,N-Dimethylacrylamide by Site Transformation of Chain Ends, Designed Monomers and Polymers 9, 63-79 (2006) -- Details |
| 232. Mori, H.; Müller, A.H.E.: Design of novel polymeric architectures with (meth)acrylic acid segments by controlled/living polymerizations in J. Jagur-Grodzinski, Ed.: Collective Volume on Living and Controlled Polymerization: Synthesis, Characterization and Properties of the Respective Polymers and Copolymers, Nova Science Publ., Happauge, N.Y., p. 257 (2006) -- Details |
| 222. André, X.; Zhang, M.; Müller, A.H.E.: Thermo- and pH-Responsive Micelles of Poly(acrylic acid)-block-Poly(N,N-diethylacrylamide), Makromolekulare Chemie Rapid Communications 26, 558-563, published on the web April 1, 2005 (2005) -- DOI: 10.1002/marc.200400510 -- Details |
| 218. Loos, K.; Böker, A.; Zettl, H.; Zhang, M.; Müller, A.H.E.; Krausch, G.: Micellar Aggregates of Amylose-block-Polystyrene Rod-Coil Block Copolymers in Water and THF, Macromolecules 38, 873-879 (2005) -- DOI: 10.1021/ma0345549 -- Details |
| 216. André, X.; Benmohammed, Kh.; Yakimansky, A.V.; Müller, A.H.E.: Anionic Block Copolymerization of N,NDiethylacrylamide in the Presence of Et3Al. Kinetic Investigations using In-Situ FT-NIR Spectroscopy In-Situ FT-NIR Spectroscopy Proceedings, 40th IUPAC Symposium on Macromolecules , MACRO 2004, Paris, July (2004) -- Details |
| 215. André, X.; Müller, A.H.E.; Charleux, B.: Remarkable Stabilization of Latex Particles by a Thermo- and pH-Responsive Block Copolymer of Poly(acrylic Acid)-b-poly(N,N-diethylacrylamide) Proceedings, 40th IUPAC Symposium on Macromolecules , MACRO 2004, Paris, July (2004) -- Details |
| 213. Pergushov, D.V.; Gradzielski, M.; Remizova, E.V.; Burkhardt, M.; Zezin, A.B.; Kabanov, V.A.; Müller, A.H.E.: Novel Micellar Architectures Based on Interpolyelectrolyte Complexes of Ionic Amphiphilic Diblock Copolymers Proceedings, 40th IUPAC Symposium on Macromolecules , MACRO 2004, Paris, July (2004) -- Details |
| 209. Schilli, C.; Zhang, M.; Müller, A.H.E.; Rizzardo, E.; Thang, S.H.; Chong, Y.K.; Edwards, K.; Karlsson, G.: A New Double-Responsive Block Copolymer Synthesized via RAFT Polymerization: , Macromolecules 37, 7861 (2004) -- Details |
| 207. Cai, Y.; Hartenstein, M.; Müller, A.H.E.: Synthesis of Amphiphilic Graft Copolymers of n-Butyl Acrylate and Acrylic Acid by Atom Transfer Radical Copolymerization of Macromonomers , Macromolecules 37, 7484 (2004) -- Details |
| 206. Müller, A.H.E.; Cai, Y.; Hartenstein, M.; Gradzielski, M.; Zhang, M.; Mori, H.; Pergushov, D.V.: Effect of topology on the aqueous solution behavior of amphiphilic block and graft copolymers of n-butyl acrylate and acrylic acid, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 45(2), 267 (2004) |
| 205. Pergushov, D.V.; Gradzielski, M.; Burkhardt, M.; Remizova, E.V.; Zezin, A.B.; Kabanov, V.A.; Müller, A.H.E.: Novel core-shell-corona architectures via complexation of micelles of ionic amphiphilic diblock copolymers with oppositely charged polyelectrolytes, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 45(2), 267 (2004) |
| 204. André, X.; Schilli, C.; Müller, A.H.E.; Charleux, B.: Double-stimuli responsive block copolymers of acrylic acid, N,N-diethylacrylamide, and N-isopropylacrylamide, Macromol. Mater. Eng. 91 (2004) -- Details |
| 193. Förster, S.; Abetz, V.; Müller, A.H.E.: Polyelectrolyte Block Copolymer Micelles, Advances in Polymer Science 166, 173 (2004) -- Details |
| 192. Bohrisch, J.; Eisenbach, C.D.; Jaeger, W.; Mori, H.; Müller, A.H.E.; Rehahn, M.; Schaller, C.; Traser, S.; Wittemeyer, P.: New Polyelectrolyte Architectures, Adv. Polym. Sci. 165, 1 (2004) |
| 187. Pergushov, D.V.; Remizova, E.V.; Gradzielski, M.; Lindner, P.; Feldthusen, J.; Zezin, A.B.; Müller, A.H.E.; Kabanov, V.A.: Micelles of Polyisobutylene-block-Poly(Methacrylic Acid) Diblock Copolymers and Their Water-Soluble Interpolyelectrolyte Complexes Formed With Quaternized Poly(4-Vinyl Pyridine), Polymer 45, 367 (2004) |
| 185. Liu, Y.; Abetz, V.; Müller, A.H.E.: Janus Cylinders, Macromolecules 36, 7894 (2003) -- Details |
| 183. Martinez-Castro, N.; Lanzendörfer, M.; Müller, A.H.E.; Cho, J.C.; Acar, M.H.; Faust, R.: Polyisobutylene stars and polyisobutylene-block-poly(tert-butyl methacrylate) block copolymers by site transformation of thiophene end-capped polyisobutylene chain ends, Macromolecules 36, 6815 (2003) -- Details |
| 182. Mori, H.; Müller, A.H.E.: New Polymeric Architectures with (Meth)acrylic Acid Segments, Progress in Polymer Science 28, 1403 (2003) -- Details |
| 181. Müller, A.H.E.; André, X.; Charleux, B.: Anionic Block Copolymerization of N,N-Diethylacrylamide. Applications for Double-Stimuli Responsive Micelle, e-Polymers P_2003 (2003) |
| 180. Pergushov, D.V.; Remizova, E.V.; Zezin, A.B.; Müller, A.H.E.; Kabanov, V.A.: Novel water-soluble micellar interpolyelectrolyte complexes, J. Phys. Chem. C. 107, 8093 (2003) -- Details |
| 172. Erhardt, R.; Zhang, M.; Böker, A.; Zettl, H.; Abetz, C.; Frederik, P.; Krausch, G.; Abetz, V.; Müller, A.H.E.: Amphiphilic Janus Micelles with Polystyrene and Poly(methacrylic acid) Hemispheres, Journal of the American Chemical Society 125, 3260-3267 (2003) -- DOI: 10.1021/ja028982q -- Details |
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