|279. Walther, A.; Hoffmann, M.; Müller, A.H.E.: Emulsion Polymerization Using Janus Particles as Stabilizers, Angew. Chem. Int. Ed. 47, 711 (2008) -- DOI: 10.1002/anie.200703224 -- PDF|
Emulsion polymerization of different monomers has been carried out using Janus particles as stabilizers. This novel type of stabilizer uniquely combines Pickering effect and amphiphilicity and leads to extremely well-defined and stable latex dispersions. The Pickering emulsion polymerizations can be conducted in a facile fashion similar to conventional emulsion polymerization and do not require homogenization procedures very common for miniemulsion polymerization routes. Furthermore, it is found that only a few Janus beads are necessary on a latex particles surface to sufficiently stabilize the dispersion against coagulation.
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- Projekt: DFG MU896/24 (ESF-SONS): Biofunctional Self-Organized Nanostructures (ESF-Projekt BIOSONS)