|357. Zhang, W.; Müller, A.H.E.: A Click Chemistry Approach to Linear and Star-Shaped Telechelic POSS-Containing Hybrid Polymers, Macromolecules 43, 3148 (2010) -- DOI: 10.1021/ma902830f|
Alkyne-POSS with good solubility was successfully synthesized using aminopropylheptaisobutyl polyhedral oligomeric silsesquioxane (POSS). Monochelic, di- and penta-telechelic POSS-containing polystyrenes were respectively prepared by the combination of ATRP and click chemistry. Here, we provide a simple and versatile method to prepare telechelic POSS-containing hybrid polymers.
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- Project: Alexander von Humboldt-Stiftung: Synthesis, self-assembly and properties of hybrid polymers based on polyhedral oligomeric silsesquioxane (POSS) molecules