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Fakultät für Biologie, Chemie und Geowissenschaften

Makromolekulare Chemie I: Prof. Hans-Werner Schmidt

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Erten-Ela, S.; Brendel, J.; Thelakkat, M.: Solid-state dye-sensitized solar cells fabricated with nanoporous TiO2 and TPD dyes: Analysis of penetration behavior and I–V characteristics, Chemical Physics Letters, 510(1-3), 93-98 (2011) -- DOI: 10.1016/j.cplett.2011.05.005
We present the synthesis, electrochemical properties and device-based investigation of triphenylene diamine (TPD) sensitizer with an extended π system consisting of donor, electron conducting and anchoring group for solid-state dye-sensitized solar cells. Solid-state dye-sensitized solar cells were fabricated using blocking TiO2 electrodes, nanoporous TiO2 electrodes and the organic hole-transporting medium, HTM (spiro-OMeTAD) in a fluorine doped tin oxide/blocking TiO2/nanoporous TiO2/TPDs/hole transport material/Au configuration. Solid state dye sensitized solar cell consisting of TPD_2 as sensitizer on mesoporous TiO2 shows the best results with a short-circuit current of 2.8 mA/cm2, an open circuit voltage of 835 mV and an overall conversion efficiency of 0.97%
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