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Faculty for Biology, Chemistry, and Earth Sciences

Macromolecular Chemistry I:

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Schmidt, M.; Wittmann, J.J.; Kress, R.; Schmidt, H.-W.; Senker, J.: Probing self-assembled 1,3,5-benzenetrisamides in isotactic polypropylene by 13C DQ solid-state NMR spectroscopy, Chemical Communications, 49, 267-269 (2013) -- DOI: 10.1039/c2cc37384j
Using 13C double quantum solid-state NMR spectroscopy, we were able to observe nuclei of a supramolecular BTA based additive on the nanoscale in a matrix of i-PP at a concentration of only 0.09 wt%. These nuclei exhibit the analogous structural features as the crystalline phase of the neat additive.
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