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Faculty for Biology, Chemistry, and Earth Sciences

Macromolecular Chemistry I:

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Bauer, P.; Sommer, M.; Thurn, J.; Pärs, M.; Köhler, J.; Thelakkat, M.: A photoswitchable poly(3-hexylthiophene), Chemical Communications, 49, 4637-4639 (2013) -- DOI: 10.1039/C3CC41765D
A well-defined main-chain conjugated photoswitchable poly(3-hexylthiophene) with homogeneous hydrogen end groups was synthesized. Opening and closing the photoswitch enables reversible modulation of P3HT emission, which is quenched by 70% when the switch is closed. The optical properties during switching cycles were quantified by irradiation/spectroscopy sequences.
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