Arbeitsgebiete: Stephan Weiß
Synthesis of Hetero-Grafted Block-Type Brushes by a
Combination of RAFT and ATRP
A synthetic strategy was evaluated towards a novel amphiphilic block-type hetero-grafted cylindrical polymer brush (CPB) via the “grafting from” approach. The diblock copolymer backbone that acted as a polymacroinitiator was prepared via reversible addition-fragmentation chain transfer (RAFT) polymerization and the side chains were grown from the backbone via atom transfer radical polymerization (ATRP).
Macro-
initiator
initiator
RAFT
Diblock
ATRP
Rod-coil-brush
ATRP
block-type hetero-grafted CPB
ATRP
AFM and SEM image of the „head of
Medusa“-like macromolecules
Medusa“-like macromolecules
AFM height and phase image of
block-type hetero-grafted CPBs
block-type hetero-grafted CPBs
„head of Medusa“:
micellous core with CPB arms
micellous core with CPB arms