Logo JG-Universität MainzProf. Dr. Axel Müller

    

Macromolecular Design: Synthesis of New Polymer Structures

Macromolecular Design

  • Branched Polymers
    Comb-Shaped, Star-Shaped, and Hyperbranched Polymers
    Planar, Spherical, and Cylindrical Polymer Brushes
    Effect of Topology and Composition on Solution and Melt Properties

  • Functional Polymers
    Polymers with Labels
    Macromonomers,
    Polyelectrolytes
    Polymers with Sugar Functions
    Pharmacologically Active Polymers
    Biocidal Polymers for Smart Coatings

  • Block, Starblock, and Graft Copolymers (AB, ABA, ABC)
    Thermoplastic Elastomers and Impact Modifiers
    Compatibilizers for Polymer Blends
    Lateral Structuring of Surfaces
    Orientation of Microdomains Induced by Shear Fields and Electrical Fields
    Stimuli-Sensitive Nanoporous Membranes

  • Amphiphilic Copolymers
    Self-Organization of Amphiphilic Block and Graft Copolymers
    Self-Organization of Stimuli-sensitive Block Copolymers
    Covalent/Reversible Networks

  • Amphiphilic Nanoparticles
    Janus Micelles and Super-Micelles
    Janus Cylinders
    Amphiphilic Core-Shell Cylinder Brushes

  • Polymer and Block Copolymer Blends
    Improvement of Macroscopic Material Properties via Compatiblization by

  • Polymer Brushes
    Hyperbranched Polymers on Planar and Spherical Substrates
    Cylindrical Brushes (Bottlebrushes)

  • Bio-Hybrid Polymers
    Rod-Coil Block Copolymers with Amylose
    Polymer-Protein Conjugates
    Sugar-containing Branched Polymers

  • Inorganic-Organic Hybrid Polymers
    Magnetizable Nanocylinders
    Metal and Semiconductor Nanowires

Controlled/Living Polymerization: Mechanisms and Kinetics

  • Anionic Polymerization
  • Group Transfer Polymerization
  • Cationic Polymerization
  • Controlled Radical Polymerization (ATRP, RAFT)
  • Multi-Mode Polymerization
Development of Polymerization Reactors
  • Continuous Flow/ Quenched Flow
  • Stopped Flow
  • In-situ FT-NIR Kinetics

Polymer Analysis and Molecular Characterization

  • GPC with Multi-Angle Light Scattering (MALS) and Viscosity Detectors
  • HPLC under Critical Conditions of Adsorption (LACCC)
  • 2D Chromatography (LACCC + SEC)
  • Asymmetric Flow Field Flow Fractionation (AF4) with MALS Detector
  • Static and Dynamic Light Scattering
  • Fluorescence Correlation Spectroscopy
  • MALDI-TOF Mass Spectrometry
  • Membrane Osmometry

Structural and Thermal Characterization of Polymers

  • Transmission Electron Microscopy (including Cryo-TEM)
  • Scanning Electron Microscopy
  • Scanning Force Microscopy (AFM)
  • SAXS, WAXS, SANS
  • Rheology and Rheooptics
  • DSC, TGA, DMTA

powered by php + PostgreSQL - last modified 2004-12-23- Impressum