Logo JG-Universität MainzProf. Dr. Axel Müller


252. Baskaran, D.; Müller, A.H.E.: Anionic Vinyl Polymerization – 50 Years After Michael Szwarc, Prog. Polym. Sci. 32, 173 (2007)

We present a review on the present status of anionic polymerization of important non-polar and polar vinyl monomers. After presenting the historical background – the "pre-Szwarc" era – we discuss the mechanisms of this polymerization, in particular several types of carbanions, their ion-pairs and their aggregates occurring in the initiation and propagation of non-polar and polar monomers, including recent developments. Finally, we discuss some important scientific and industrial applications of anionic polymerization.

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